I don't believe so, but having said that, I don't have one near me to try it either.
I'd give it a "tentative no".
It does not, it can only copy a single sided original, but can output to 2-sided, so when you go to the Duplex option you will have
Does xerox workcenter 3225 support auto duplex scanning and duplex copying?
As far as i understood by reading the settings, it supports duplex printing for sure.
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