Word uses the last used settings until it is completely closed, so I would assume you set the preferences without closing Word, or rebooting. Simplest thing is to reboot and see what happens, but you can verify by simply opening the driver within Word and making sure it is populated
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I have a WC7855 with a Fiery and the client wants user codes. I setup the Xerox Standard accounting and the copying works as expected. I go into Printing Preferences, Job Info and plug in Account ID and User ID. I can now print a Windows test print, but I can not print out of Word. Am I missing something?